Pure rac ansa-lanthanocene alkyl complexes have been directly isolated and structurally characterized; they feature a rigid unsymmetric structure with the alkyl group paralleling the bridged indenyl planes.
C. Qian, G. Zou and J. Sun, J. Chem. Soc., Dalton Trans., 1999, 519 DOI: 10.1039/A808719I
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