Issue 18, 1999

Intramolecular alkylation of an α-sulfinyl vinylic carbanion without loss of optical purity: a novel access to chiral cyclic vinylic sulfoxides

Abstract

Novel cyclisation via intramolecular α-alkylation of vinylic sulfoxides was studied and cyclic vinylic sulfoxides of various ring sizes (5–7) were synthesised from both (E)- and (Z)-isomers without loss of optical purity.

Article information

Article type
Paper

Chem. Commun., 1999, 1825-1826

Intramolecular alkylation of an α-sulfinyl vinylic carbanion without loss of optical purity: a novel access to chiral cyclic vinylic sulfoxides

N. Maezaki, M. Izumi, S. Yuyama, C. Iwata and T. Tanaka, Chem. Commun., 1999, 1825 DOI: 10.1039/A905320D

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