Issue 12, 1999
From the journal:

Chemical Communications

Cyclam as a supramolecular synthon: infinite stacked arrays to encapsulation in superanions

Samantha Airey,   Alexander Drljaca,   Michaele J. Hardie  and  Colin L. Raston  

Abstract

Cyclam crystallised from CHCl3–hexane gives infinite, hydrogen bonded assembled columns; in acidic aqueous media (pH 2) in the presence of sodium p-sulfonatocalix[4]arene and the dichromium(III) aqua ion, the superanion or ionic capsule [[H4(cyclam)]4+ ⊂ {(p-sulfonatocalix[4]arene4–)2}]4– crystallises as the salt of [Cr2(OH)2(H2O)8]4+.

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Article information

DOI
https://doi.org/10.1039/A902124H
Article type
Paper

Chem. Commun., 1999, 1137-1138

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Cyclam as a supramolecular synthon: infinite stacked arrays to encapsulation in superanions

S. Airey, A. Drljaca, M. J. Hardie and C. L. Raston, Chem. Commun., 1999, 1137 DOI: 10.1039/A902124H

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