At a TEMPO-modified graphite felt electrode (TMGFE) rac-1-phenylethanol 2 is not enantioselectively oxidised in the presence of (–)-sparteine 1, but instead 1 is dehydrogenated to its iminium salt; 2 is oxidised in solution by the oxoammonium salt 6 in the absence of 1, but not on the TMGFE in the range 0–1.0 V vs. Ag/AgNO3.
E. M. Belgsir and H. J. Schäfer, Chem. Commun., 1999, 435 DOI: 10.1039/A809789E
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