Issue 5, 1999
From the journal:

Chemical Communications

Novel zwitterionic complexes of Ti(IV) via reaction of Lewis acids M(C6F5)3 (M = B, Al) with a titanium diene complex (η5-C5Me4SiMe2NtBu)Ti(1,3-pentadiene)

Alan H. Cowley,   Gregory S. Hair,   Brian G. McBurnett  and  Richard A. Jones  

Abstract

The reaction of (η5-C5Me4SiMe2NtBu)Ti(1,3-pentadiene) with B(C6F5)3 or Al(C6F5)3 in 1:1 mole ratio in hexane solution at room temperature results in the formation of titanium borate or aluminate zwitterions which both feature stabilisation of the Ti(IV) centre by two agostic Ti⋯H–C interactions.

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DOI
https://doi.org/10.1039/A809438A
Article type
Paper

Chem. Commun., 1999, 437-438

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Novel zwitterionic complexes of Ti(IV) via reaction of Lewis acids M(C6F5)3 (M = B, Al) with a titanium diene complex (η5-C5Me4SiMe2NtBu)Ti(1,3-pentadiene)

A. H. Cowley, G. S. Hair, B. G. McBurnett and R. A. Jones, Chem. Commun., 1999, 437 DOI: 10.1039/A809438A

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