SCHEDULED MAINTENANCE
Novel intramolecular radical spirocyclisation reactions in aromatic nuclei, 48→49, 40→22 and 34→32, are presented, which mimic a key step in the proposed biosynthesis of the interiorins 2a–d, the kadsulignans 3a,b and relatives.
S. P. Green and D. A. Whiting, J. Chem. Soc., Perkin Trans. 1, 1998, 193 DOI: 10.1039/A706589B
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