An attempt to synthesise a new protected serine derivative led to the isolation of N-tetrachlorophthaloyldehydroalanine methyl ester, which underwent Michael addition of dialkyl malonates to form γ-carboxyglutamic acid derivatives.
M. Caillard, A. Emm, A. Jones, T. Matthews and J. Michael Williams, J. Chem. Res. (S), 1998, 806 DOI: 10.1039/A806463F
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