As possible candidates for intermediates in brassinolide biosynthesis, (22S)-22-hydroxycampesterol 1 and its related new steroids 5–7 are conveniently synthesized by employing a Grignard reaction of a known steroidal 22-aldehyde 8 with 2,3-dimethylbutylmagnesium bromide as a key reaction.
S. Takatsuto, T. Watanabe, C. Gotoh, H. Kuriyama, T. Noguchi and S. Fujioka, J. Chem. Res. (S), 1998, 176 DOI: 10.1039/A707201E
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