The 2-(alkoxycarbonyl)allylsilane moiety acts simultaneously as both nucleophile and electrophile when ethyl 10-oxo-2-(trimethylsilylmethyl)undec-2-en-8-ynoate is treated with tetrabutylammonium fluoride.
C. Kuroda, Y. Kimura and H. Nogami, J. Chem. Res. (S), 1998, 174 DOI: 10.1039/A706697J
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