Palladium-catalysed Cyclisation and Cyclisation–Carbonylation of Unsaturated C-Glycoside Derivatives. The Importance of Relative Stereochemistry
Abstract
The Pd-catalysed `metallo-ene type' cyclisation and cyclisation–carbonylation of selected 2,3-unsaturated C-glycosides is described and attention is drawn to the importance of relative stereochemistry in the latter type of reactions.