The hydrolysis of the monoribonucleotide GpppG, a model compound for the 5′-cap structure of mRNA, by dinuclear Cu(II) complexes of triazacyclononane was 100-fold more rapid than in the presense of the analogous mononuclear complex; a first-order or second-order dependence on the catalyst was observed for two different dinuclear complexes.
K. P. McCue, D. A. Voss, D. A. V. Jr., C. M. J. R. M., C. Marks and J. R. Morrow, J. Chem. Soc., Dalton Trans., 1998, 2961 DOI: 10.1039/A805916K
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