Issue 16, 1998

Desulfurisation of trithiocarbonates at a dimolybdenum centre: an unexpected insertion into a co-ordinated alkyne

Abstract

On reaction with the dimolybdenum alkyne complex [Mo2{µ-C2(CO2Me)2}(CO)4(η-C5H5)2], dialkyl trithiocarbonates (RS)2C[double bond, length half m-dash]S were dismantled into sulfido (µ-S), thiolate (µ-SR) and CSR fragments; remarkably the last of these inserts into the middle of the alkyne to produce a dimetalla-allyl species with a µ-C(CO2Me)C(SR)C(CO2Me) ligand.

Supplementary files

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 2607-2610

Desulfurisation of trithiocarbonates at a dimolybdenum centre: an unexpected insertion into a co-ordinated alkyne

H. Adams, C. Allott, M. N. Bancroft and M. J. Morris, J. Chem. Soc., Dalton Trans., 1998, 2607 DOI: 10.1039/A804138E

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