Issue 23, 1998
From the journal:

Chemical Communications

Supramolecular cation of an acyclic polyether: potassium(pentaethylene glycol) in a molecular conducting nickel dithiolate salt

Tomoyuki Akutagawa,   Tatuso Hasegawa,   Takayoshi Nakamura,   Tomoyuki Akutagawa,   Yu-ichiro Nezu,   Tatuso Hasegawa,   Takayoshi Nakamura,   Ken-ichi Sugiura,   Yoshiteru Sakata,   Tamotsu Inabe  and  Allan E. Underhill  

Abstract

The X-ray structural analysis of the title compound revealed the formation of segregated [Ni(dmit)2] (dmit = 2-thioxo-1,3-dithiol-4,5-dithiolate) columns and dimeric K+2[PEG]2 (PEG = pentaethylene glycol) supramolecular cations in the crystal; the interaction between K+ and acyclic PEG was found to be weaker that that between K+ and cyclic polyether 18-crown-6.

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Article information

DOI
https://doi.org/10.1039/A807474G
Article type
Paper

Chem. Commun., 1998, 2599-2600

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Supramolecular cation of an acyclic polyether: potassium(pentaethylene glycol) in a molecular conducting nickel dithiolate salt

T. Akutagawa, T. Hasegawa, T. Nakamura, T. Akutagawa, Y. Nezu, T. Hasegawa, T. Nakamura, K. Sugiura, Y. Sakata, T. Inabe and A. E. Underhill, Chem. Commun., 1998, 2599 DOI: 10.1039/A807474G

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