Issue 18, 1998

New sulfide-bridged heterocubanes [MVI(S)ReI3(CO)93-S)4], M = Mo or W, with transition metals in very different oxidation states

Abstract

The cluster anions [MVI(S)ReI3(CO)93-S)4], M = Mo or W, contain three six-coordinate tricarbonylrhenium(I) fragments, held together by one µ3-sulfide ion and by one reducible and charge transfer-active µ3-MVIS42– unit.

Article information

Article type
Paper

Chem. Commun., 1998, 2055-2056

New sulfide-bridged heterocubanes [MVI(S)ReI3(CO)93-S)4], M = Mo or W, with transition metals in very different oxidation states

F. M. Hornung, K. Wilhelm Klinkhammer and W. Kaim, Chem. Commun., 1998, 2055 DOI: 10.1039/A805295F

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