(R)-3-Hydroxybutan-2-one was obtained with 85–90% ee albeit in low yield by the Pt/Al2O3 cinchona catalyzed hydrogenation of butane-2,3-dione by a combination of enantioselective hydrogenation and kinetic resolution.
M. Studer, H. Blaser, M. Studer, V. Okafor and H. Blaser, Chem. Commun., 1998, 1053 DOI: 10.1039/A801390J
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