Issue 9, 1998

Reaction behaviour of a complex containing a tungsten phosphorus triple bond with ς-acceptor compounds of group 13

Abstract

[LW[triple bond, length half m-dash]P→GaCl3] 5 [L = N(CH2CH2NSiMe3)3] is prepared by treatment of [LW[triple bond, length half m-dash]P] with (GaCl3)2; decomposition of 5 in CH2Cl2 affords dimerisation under Me3SiCl elimination to give a cationic W2P2 tetrahedral complex 6; both complexes are structurally characterised.

Article information

Article type
Paper

Chem. Commun., 1998, 1051-1052

Reaction behaviour of a complex containing a tungsten phosphorus triple bond with ς-acceptor compounds of group 13

M. Scheer, J. Müller, G. Baum, M. Scheer, J. Müller, G. Baum and M. Häser, Chem. Commun., 1998, 1051 DOI: 10.1039/A801136B

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