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Sceletium A-4, a pyridine alkaloid isolated from the Sceletium species, has been synthesized for the first time in an enantiocontrolled manner along with (–)-mesembrine, an alkaloid isolated from the same plant, starting from a chiral cyclohexadienone synthon to determine the absolute configuration.
T. Kamikubo and K. Ogasawara, Chem. Commun., 1998, 783 DOI: 10.1039/A709212A
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