Asymmetric tandem cycloaddition of a chiral carbohydrate nitroalkene with ethyl vinyl ether in the presence of electron- withdrawing alkenes produces a facile assembly of bicyclic systems, which can further be selectively cleaved to give homologated carbohydrates.
M. Avalos, P. Cintas, J. L. Jiménez and J. C. Palacios, Chem. Commun., 1998, 459 DOI: 10.1039/A708222C
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