By far the shortest hydrogen bonds of the O–H···S type occur in monothio-ß-diketones and related substances (H···S distances 1.9–2.0 Å); it is shown with crystal correlation techniques that this very short hydrogen bonding is facilitated by resonance assistance similar to that occurring in the oxygen analogues.
T. Steiner, Chem. Commun., 1998, 411 DOI: 10.1039/A707434D
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