Issue 5, 1998

A chlorophobic pocket in the p-tert-butylcalix[4]arene cavity: a test site for molecular recognition investigated by 13C CP MAS NMR and X-ray crystallography†

Abstract

Five-membered aliphatic guests X(CH2)3Y (X, Y = Me, OH, Cl, Br) adopt equilibrium positions in the asymmetric p-tert-butylcalix[4]arene cavity formed in the solid state and reveal a marked aversion of the host pocket for halogen end-groups.

Article information

Article type
Paper

Chem. Commun., 1998, 587-588

A chlorophobic pocket in the p-tert-butylcalix[4]arene cavity: a test site for molecular recognition investigated by 13C CP MAS NMR and X-ray crystallography†

E. B. Brouwer, K. A. Udachin, G. D. Enright, C. I. Ratcliffe, J. A. Ripmeester, E. B. Brouwer, G. D. Enright and J. A. Ripmeester, Chem. Commun., 1998, 587 DOI: 10.1039/A705508K

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