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Issue 22, 1997
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Enantiospecific total synthesis of (+)-2-pupukeanone

Abstract

The first total synthesis of chiral 2-pupukeanone (+)-4, starting from R-carvone (–)-7 employing a 5-exo-trig radical cyclisation as the key reaction for the construction of the tricyclic isotwistane carbon framework, is described.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1997, 3293-3294
Article type
Paper

Enantiospecific total synthesis of (+)-2-pupukeanone

A. Srikrishna and T. Jagadeeswar Reddy, J. Chem. Soc., Perkin Trans. 1, 1997, 3293
DOI: 10.1039/A706321K

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