Total synthesis of (±)-α-pinguisene 1 and (±)-pinguisenol 2, employing an orthoester Claisen rearrangement and an intramolecular diazo ketone cyclopropanation reaction for the stereospecific construction of vicinal quaternary carbon atoms, is described.
A. Srikrishna and D. Vijaykumar, J. Chem. Soc., Perkin Trans. 1, 1997, 3295 DOI: 10.1039/A705600A
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