It has been shown by using MP2(fc)/6-31G** and MP2(fc)/6-311+ +G** methods that the internal rotation of H2BNBH2- and H2BOBH2 allene structures occurs through the corresponding angle structures with a very small energy barrier.
R. M. Minyaev and E. A. Lepin, Mendeleev Commun., 1997, 7, 80 DOI: 10.1070/MC1997v007n02ABEH000717
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