Issue 15, 1997
From the journal:

Journal of the Chemical Society, Dalton Transactions

Oxidative and reductive activation of tetra-n-butylammonium trans-tetrabromobis(tert-butylisocyanide)ruthenium( III): a spectroelectrochemical study

Joseph P. al Dulaimi,   Robin J. H. Clark  and  David G. Humphrey  

Abstract

Electrochemical and spectroelectrochemical studies have shown that oxidation of trans-[RuBr 4 (CNBu t ) 2 ] - in acetonitrile produces tervalent mer,trans-[RuBr 3 (CNBu t ) 2 (NCMe)], whilst reduction leads to the formation of a divalent complex of the same stoichiometry, mer,trans-[RuBr 3 (CNBu t ) 2 (NCMe)] - , which can be oxidised reversibly to mer,trans-[RuBr 3 (CNBu t ) 2 (NCMe)].

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Article information

DOI
https://doi.org/10.1039/A703245E
Article type
Paper

J. Chem. Soc., Dalton Trans., 1997, 2535-2536

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Oxidative and reductive activation of tetra-n-butylammonium trans-tetrabromobis(tert-butylisocyanide)ruthenium( III): a spectroelectrochemical study

J. P. al Dulaimi, R. J. H. Clark and D. G. Humphrey, J. Chem. Soc., Dalton Trans., 1997, 2535 DOI: 10.1039/A703245E

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