SCHEDULED MAINTENANCE
Reactions of transition-metal oxo complexes with B(C6F5)3: crystal structures of [V{OB(C6F5)3} (acac)2], [Ti{OB(C6F5)3} (acac)2] and cis-[MoO{OB(C6F5 )3}(acac)2] (acac = acetylacetonate)
Abstract
The transition-metal oxo complexes [VO(acac)
2
],
[{TiO(acac)
2
}
2
] and
cis-[MoO
2
(acac)
2
]
(acac = C
5
H
7
O
2
) reacted
with the strong Lewis acid B(C
6
F
5
)
3
to
give the structurally characterized complexes
[V{OB(C
6
F
5
)
3
}(acac)
2
],
[Ti{OB(C
6
F
5
)
3
}(acac)
2
] and
cis-[MoO{OB(C
6
F
5
)
3
}
(acac)
2
]. The M![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
O–B moiety is
essentially linear.
O–B moiety is
essentially linear.
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