Diols with excellent enantiomeric excesses are obtained from unfunctionalised alkenes in high yields by osmium-catalyseddihydroxylations using silica-bound pyrimidine and pyrazino-pyridazine ligands.
C. Bolm and A. Gerlach, Chem. Commun., 1997, 2353 DOI: 10.1039/A706605H
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