Issue 24, 1997

Chiral ruthenium complexes as catalysts in enantioselective Diels–Alder reactions. Crystal structure of the Lewis acid–dienophile adduct

Abstract

On the basis of spectroscopic and structural studies a full catalytic cycle is proposed for the Diels–Alder reaction between methacrolein and cyclopentadiene when the new chiral aquo-complexes (RRu, SRu)-[(η6-p-cymene)Ru(PN)(H2O)][SbF6]2 {PN = (3aS, 8aR)-2-(2-diphenylphosphinophenyl)-3a,8a-dihydroindane[1,2-d]oxazole} are used as catalysts.

Article information

Article type
Paper

Chem. Commun., 1997, 2351-2352

Chiral ruthenium complexes as catalysts in enantioselective Diels–Alder reactions. Crystal structure of the Lewis acid–dienophile adduct

D. Carmona, S. Elipe, F. J. Lahoz, L. A. Oro, C. Cativiela, M. Pilar López-Ram de Víu, M. Pilar Lamata, C. Vega and F. Viguri, Chem. Commun., 1997, 2351 DOI: 10.1039/A705605B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements