Chiral 2,2′:6′,2″:6″,2′′′-quaterpyridines bearing fused chiral groups in the 5,6- and 5′′′,6′′′-positions are prepared; these ligands preferentially form P or M dinuclear double helicates upon coordination to silver(I), one of which has been structurally characterised.
E. C. Constable, T. Kulke, G. Baum and D. Fenske, Chem. Commun., 1997, 2043 DOI: 10.1039/A705130A
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