Issue 17, 1997

Unexpectedly selective ligand binding within the cavity of a cyclic metalloporphyrin dimer

Abstract

4-Substituted pyridines of an appropriate size show a remarkable preference for binding inside the cavity of a cofacial butadiyne-linked zinc porphyrin dimer; the origin of the effect is not entirely clear but may be related to solvent release or favourable host–guest contacts

Article information

Article type
Paper

Chem. Commun., 1997, 1611-1612

Unexpectedly selective ligand binding within the cavity of a cyclic metalloporphyrin dimer

R. Stephen Wylie, E. G. Levy and J. K. M. Sanders, Chem. Commun., 1997, 1611 DOI: 10.1039/A702901B

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