Issue 11, 1997

Tandem prop-2-ynyl carbenoid–aldehyde insertion into zirconacycles

Abstract

Insertion of 1-lithio-1-chloroalk-2-ynes into zirconacycles gives cyclic zirconocene η 3 -prop-2-ynyl/allenyl complexes which afford useful organic products on protonation or Lewis acid induced addition of aldehydes.

Article information

Article type
Paper

Chem. Commun., 1997, 1045-1046

Tandem prop-2-ynyl carbenoid–aldehyde insertion into zirconacycles

G. J. Gordon and R. J. Whitby, Chem. Commun., 1997, 1045 DOI: 10.1039/A701592E

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