Issue 9, 1997

Stepwise oxidation of a µ-alkylidene palladium–tungsten compound

Abstract

The µ-alkylidene unit of a tungsten–palladium compound is oxidized to the corresponding ketone in the presence of an excess of Me 3 NO, whereas with 2–4 equiv., mono- and di-oxotungsten derivatives, which are likely intermediates in the formation of the ketone, are instead obtained.

Article information

Article type
Paper

Chem. Commun., 1997, 871-872

Stepwise oxidation of a µ-alkylidene palladium–tungsten compound

P. F. Engel, M. Pfeffer, A. De Cian and J. Fischer, Chem. Commun., 1997, 871 DOI: 10.1039/A700741H

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