Synthesis, derivatization, and structural characterization of [Mn(CNC6H3Me2-2,6)5] -, a five-coordinate isonitrilate complex containing Mn-I
Abstract
Naphthalenide reduction of
[Mn(CNC
6
H
3
Me
2
-2,6)
5
Cl] forms
solutions of trigonal-bipyramidal
[Mn(CNC
6
H
3
Me
2
-2,6)
5
]
-
, as established by an X-ray diffraction study of a
[K(18-C-6)(dme)]
+
salt and derivatization with
SnClPh
3
to give
[Mn(CNC
6
H
3
Me
2
-2,6)
5
(SnPh
3
)].
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