Issue 5, 1997

Hydride and proton transfer reactions in gaseous ion–molecule complexes [PhCH2+ HOCH2CH2OH]

Abstract

Benzyl cations and ethylene glycol react in the gas phase and form covalently bound adducts, as shown by slow and site-selective proton exchange, but also undergo irreversible hydride transfer giving two ion–neutral complexes, [PhCH 3 HOCH 2 CHOH + ] and [PhHCH 3 + HOCH 2 CHO], which interconvert by a rapid and non-selective proton exchange.

Article information

Article type
Paper

Chem. Commun., 1997, 429-430

Hydride and proton transfer reactions in gaseous ion–molecule complexes [PhCH2+ HOCH2CH2OH]

H. E. Audier, F. Dahhani, A. Milliet and D. Kuck, Chem. Commun., 1997, 429 DOI: 10.1039/A607744G

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