Non-polymeric molybdenum(ii) complexes of dicarboxylic acids: synthesis, structure and catalytic properties
Abstract
[Mo
2
(MeCN)
8
][BF
4
]
4
reacts
with α,ω-dicarboxylic acids
[HO
2
C(CH
2
)
n
CO
2
H,
n = 0–8] to form salts with empirical formula
[Mo
2
{O
2
C(CH
2
)
n
C
O
2
}(MeCN)
x
][BF
4
]
2
; the X-ray crystal structure of the butanedioic salt
[Mo
4
{η
2
-µ-O
2
C-
(CH
2
)
2
CO
2
-µ-η
2
}
2
(MeCN)
12
][BF
4
]
4
·3MeCN
is reported together with the use of the complexes as catalysts for the
polymerization of norbornene.
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