The ‘diimino thioanhydrides’ of cyclohex-l-ene-1,2-dicarboxylic acid have been synthesized in a very simple manner by allowing 2-(arylaminothiocarbonyl)cyclohexanones 1 and isocyanides 3 to react in an acidic medium. A mechanism for this three-component reaction, based on isocyanide chemistry, is proposed.
R. Bossio, S. Marcaccini, R. Pepino and T. Torroba, J. Chem. Soc., Perkin Trans. 1, 1996, 229 DOI: 10.1039/P19960000229
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