Triethoxyphosphoranes 2, generated in situ from oxamates 1, reacted with bromotrimethylsilane to give α-aminophosphonic esters 3 which, in the case of example 13, have been used in a new synthesis of 1-β-methylcarbapenem 14.
M. Seki, K. Kondo and T. Iwasaki, J. Chem. Soc., Perkin Trans. 1, 1996, 3 DOI: 10.1039/P19960000003
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