In competition experiments, alkenes tethered to pyridyl groups were found to undergo iridium catalysed hydrogenation more quickly than alkenes tethered to phenyl groups. This is in marked contrast to the results for hydrogenation of some of the individual substrates where alkenes tethered to pyridyl groups were reduced much more slowly than their phenyl counterparts.
A. D. Westwell and J. M. J. Williams, J. Chem. Soc., Perkin Trans. 1, 1996, 1 DOI: 10.1039/P19960000001
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