Issue 21, 1996

First characterization of arsenic porphyrins: synthesis and X-ray structure of [(oep)AsMe(OH)]+ClO4

Abstract

[(oep)As(OH)2]ClO4 is synthesized in good yields by non-nucleophilic oxidative treatment of (oep)AsCl with pyridinium tribromide followed by hydrolysis and is converted to [(oep)AsMe(OH)]ClO4 with AlMe3.

Article information

Article type
Paper

Chem. Commun., 1996, 2451-2452

First characterization of arsenic porphyrins: synthesis and X-ray structure of [(oep)AsMe(OH)]+ClO4

W. Satoh, R. Nadano, Y. Yamamoto and K. Akiba, Chem. Commun., 1996, 2451 DOI: 10.1039/CC9960002451

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