The two-faced JANUS-type heterocycles 1a and 1b are designed to recognize a cytosine–uracil mismatched basepair by insertion in a wedge-like fashion between the bases to give a triad motif utilizing the maximum number of Watson–Crick interactions, as shown by 1H NMR spectroscopic studies.
N. Branda, G. Kurz and J. Lehn, Chem. Commun., 1996, 2443 DOI: 10.1039/CC9960002443
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