1 H/19F NMR two-dimensional exchange spectroscopy (EXSY) reveals that the 1,4-metallotropic shifts in bidentate chelate complexes of a substituted 2,2′ : 6′,2″-terpyridine ligand occur by an associative mechanism involving five-coordinate intermediates for PdII and PtII complexes, and seven-coordinate intermediates for PtIV and, by analogy, ReI complexes.
E. W. Abel, A. Gelling, K. G. Orrell, A. G. Osborne and V. Šik, Chem. Commun., 1996, 2329 DOI: 10.1039/CC9960002329
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