A pre-reactive complex H2O⋯ClF of planar (C2v) or effectively planar (Cs) geometry is characterised for the first time in mixtures of water vapour and chlorine monofluoride through its rotational spectrum, as observed with a fast-mixing nozzle/Fourier-transform microwave spectrometer.
S. A. Cooke, G. Cotti, C. M. Evans, J. H. Holloway and A. C. Legon, Chem. Commun., 1996, 2327 DOI: 10.1039/CC9960002327
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