Issue 18, 1996

Substitution on a methyl group of an acetylacetonate ligand: synthesis and structural characterization of oxobis[6-(phenylamino)hexane-2,4-dionato-O,O′]vanadium(IV), VO(Phad)2

Abstract

From a melt reaction of VO(acac)2 and N,N′-diphenylformamidine, HDPhF, the title compound is isolated in high yield along with aniline; the new ligand found in 1 arises from the cleavage of a C–N bond in the HDPhF molecule and the substitution of two hydrogen atoms from a methyl group of an acac ligand.

Article information

Article type
Paper

Chem. Commun., 1996, 2113-2114

Substitution on a methyl group of an acetylacetonate ligand: synthesis and structural characterization of oxobis[6-(phenylamino)hexane-2,4-dionato-O,O′]vanadium(IV), VO(Phad)2

D. I. Arnold, F. A. Cotton, J. H. Matonic and C. A. Murillo, Chem. Commun., 1996, 2113 DOI: 10.1039/CC9960002113

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