Reduction of [tris(tert-butyldimethylsilylamidoethyl)-amino]chlorouranium(IV)[L3UCl] with potassium gives the crystallographically characterised mixed-valence (III/IV dimer [L3U)2-µ-Cl] which acts as a source of trivalent uranium giving pentavalent [L3U![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
N-SiMe3] on reaction with trimethylsilylazide.
P. Roussel, P. B. Hitchcock, N. Tinker and P. Scott, Chem. Commun., 1996, 2053 DOI: 10.1039/CC9960002053
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