Nerol 15 is readily converted,via initial asymmetric epoxidation, into compound 2 which contains the tetrahydropyranoid core of herboxidiene 1, a potent phytotoxic compound isolated from Streptomyces sp. A7847.
M. G. Banwell, C. T. Bui, G. W. Simpson and K. G. Watson, Chem. Commun., 1996, 723 DOI: 10.1039/CC9960000723
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