The CH4/D2 exchange reaction in used as an indication of methane activation over potential oxide catalysts; Ga2O3 exhibits an exchange rate over two orders of magnitude higher than other simple oxides and this approach leads to the identification of Ga2O3/MoO3 as a selective catalyst for methane partial oxidation to methanol.
J. S. J. Hargreaves, G. J. Hutchings, R. W. Joyner and S. H. Taylor, Chem. Commun., 1996, 523 DOI: 10.1039/CC9960000523
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