Issue 13, 1995
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reaction of CH2(Ph2PSe)2 with [Ru3(CO)12]. Crystal structure of [Ru4Se4(CO)10(Ph2PCH2PPh2)], a missing link in the [M4E4L12] cubane series (M = Group 8 metal, E = chalcogenido ligand)

Daniele Cauzzi,   Claudia Graiff,   Maurizio Lanfranchi,   Giovanni Predieri  and  Antonio Tiripicchio  

Abstract

The bis(Phosphine selenide) CH2(Ph2PSe)2 and [Ru3(CO)12](1 : 1) reacted in toluene to give [Ru3(µ3-Se)2(CO)7(dppm)], [Ru4(µ4-Se)2(CO)9(dppm)] and [Ru4(µ3-Se)4(CO)10(dppm)](dppm = Ph2PCH2PPh2), the last of which is the first reported 72-electron Ru–Se cubane-like cage complex.

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Article information

DOI
https://doi.org/10.1039/DT9950002321
Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 2321-2322

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Reaction of CH2(Ph2PSe)2 with [Ru3(CO)12]. Crystal structure of [Ru4Se4(CO)10(Ph2PCH2PPh2)], a missing link in the [M4E4L12] cubane series (M = Group 8 metal, E = chalcogenido ligand)

D. Cauzzi, C. Graiff, M. Lanfranchi, G. Predieri and A. Tiripicchio, J. Chem. Soc., Dalton Trans., 1995, 2321 DOI: 10.1039/DT9950002321

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