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Issue 13, 1995
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Copper(II) chloride–1-methylbenzotriazole chemistry: variation of product as a function of metal-to-ligand reaction ratio; synthesis, structure and properties of a dinuclear complex and a novel chain polymer with two alternating chromophores

Abstract

The 1 : 2 and 1 : 1 reactions of CuCl2 with 1-methylbenzotriazole in EtOH–CH(OEt)3 gave the doubly chloro-bridged dimer [Cu2Cl4(C7H7N3)4]1 and the novel alternating linear-chain polymer [{Cu2Cl4(C7H7N3)2}n]2 respectively, crystal structures of which have been determined; magnetic susceptibility studies show that complex 1 possesses intramolecular- and complex 2 intrachain-ferromagnetic coupling.

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Article information


J. Chem. Soc., Dalton Trans., 1995, 2317-2319
Article type
Paper

Copper(II) chloride–1-methylbenzotriazole chemistry: variation of product as a function of metal-to-ligand reaction ratio; synthesis, structure and properties of a dinuclear complex and a novel chain polymer with two alternating chromophores

K. Skorda, E. G. Bakalbassis, J. Mrozinski, S. P. Perlepes, C. P. Raptopoulou and A. Terzis, J. Chem. Soc., Dalton Trans., 1995, 2317 DOI: 10.1039/DT9950002317

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