Issue 23, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Copper-promoted intramolecular selenium transfer from a P[double bond, length half m-dash]Se group to a P–CH2–P methylene carbon producing an unusual methaneselone ligand

Daniele Cauzzi,   Claudia Graiff,   Maurizio Lanfranchi,   Giovanni Predieri  and  Antonio Tiripicchio  

Abstract

The bis(diphenylphosphino)methane selenides CH2(Ph2P)Ph2PSe and CH2(Ph2PSe)2, react with copper(II) chloride giving an unidentified copper(I) complex; exposure to the air affords the new bifunctional, tridentate iigand bis(diphenylphosphoryl)methaneselone SeC(Ph2PO)2 linking copper(I) and copper(II) in the trinuclear complex [CuII{CuICl2[µ-SeC(Ph2PO)2]}2].

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Article information

DOI
https://doi.org/10.1039/C39950002443
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 2443-2444

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Copper-promoted intramolecular selenium transfer from a P[double bond, length half m-dash]Se group to a P–CH2–P methylene carbon producing an unusual methaneselone ligand

D. Cauzzi, C. Graiff, M. Lanfranchi, G. Predieri and A. Tiripicchio, J. Chem. Soc., Chem. Commun., 1995, 2443 DOI: 10.1039/C39950002443

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