Treatment of PPN[Rh(CO)4][PPN =(Ph3P)2N] with various nitro-aromatics in THF at ambient temperature produces a new class of neutral radicals; rhodium(I) species consisting of two cis carbonyl ligands and a bidentate aromatic nitro radical anion of which the nitro group and an ipso-ortho carbon double bond on the ring are bound to the rhodium centre.
P. Liu, H. Liao and C. Cheng, J. Chem. Soc., Chem. Commun., 1995, 2441 DOI: 10.1039/C39950002441
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