Issue 20, 1995

Synthesis and structure of the first trans-1,2-dihydro-1,2,3-triphosphete–tungsten complex

Abstract

Thermal decomposition of the 2H-azaphosphirene complex 1 in the presence of kinetically stabilised phosphalkynes 2a,b yields the 1H-diphosphirene complex 4a and the 1,2-dihydro-1,2,3-triphosphete complex 5; for the latter the overall reaction may be described as an insertion of a phosphanediyl complex into a ring bond of a transiently formed 1H-diphosphirene complex, with loss of one pentacarbonyltungsten moiety.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 2113-2114

Synthesis and structure of the first trans-1,2-dihydro-1,2,3-triphosphete–tungsten complex

R. Streubel, L. Ernst, J. Jeske and P. G. Jones, J. Chem. Soc., Chem. Commun., 1995, 2113 DOI: 10.1039/C39950002113

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